If bond enthalpies of $N \equiv N$,$H - H$ and $N - H$ bonds are $x_1, x_2$ and $x_3$ respectively,$\Delta H_f^o$ for $NH_3$ will be

Calculate the heat of reaction for the process: $NH_3(g) + HCl(g) \rightarrow NH_4Cl(s)$ given the following data:
$(i)$ $NH_3(g) + aq \rightarrow NH_3(aq)$,$\Delta H = -8.4 \, Kcal$
$(ii)$ $HCl(g) + aq \rightarrow HCl(aq)$,$\Delta H = -17.3 \, Kcal$
$(iii)$ $NH_3(aq) + HCl(aq) \rightarrow NH_4Cl(aq)$,$\Delta H = -12.5 \, Kcal$
$(iv)$ $NH_4Cl(s) + aq \rightarrow NH_4Cl(aq)$,$\Delta H = +3.9 \, Kcal$ (in $, Kcal$)

$XeF_{2(g)} + H_{2(g)} \to 2HF_{(g)} + Xe_{(g)}$,$\Delta H^o = -430 \ kJ$
Bond energy:
$H-H = 435 \ kJ/mol$
$H-F = 565 \ kJ/mol$
Calculate the average bond energy of the $Xe-F$ bond in $kJ/mol$.

Calculate the enthalpy change of vaporisation of benzene if $13 \ g$ of benzene vaporised by supplying $5.1 \ kJ$ of heat.

The heat evolved in the combustion of benzene is given by $C_6H_6 + 7.5 O_2 \to 6CO_2(g) + 3H_2O(l); \Delta H = -3264.6 \, kJ$. Which of the following quantities of heat energy will be evolved when $39 \, g$ of $C_6H_6$ is burnt? (in $kJ$)

Given:
$(i) \, C(\text{graphite}) + O_{2(g)} \to CO_{2(g)}; \Delta_r H^\ominus = x \, kJ \, mol^{-1}$
$(ii) \, C(\text{graphite}) + \frac{1}{2} O_{2(g)} \to CO_{(g)}; \Delta_r H^\ominus = y \, kJ \, mol^{-1}$
$(iii) \, CO_{(g)} + \frac{1}{2} O_{2(g)} \to CO_{2(g)}; \Delta_r H^\ominus = z \, kJ \, mol^{-1}$
Based on the above thermochemical equations,find out which one of the following algebraic relationships is correct?